Ming-Hsiu Hsieh
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mhhsieh.bsky.social
Ming-Hsiu Hsieh
@mhhsieh.bsky.social
PhD Candidate in Theoretical Chemistry
Tempelaar group
Northwestern University
Personal Website: https://m-h-hsieh.github.io/
Our new paper is out!

We revealed that by "focusing" the initial coordinates to have zero-point energy, our DC-MF method reproduces quantum electrodynamics reference in both small- and large-cavity regimes.

pubs.acs.org/doi/10.1021/...

@tempelaarteam.bsky.social
@nuchemistry.bsky.social
Focused Sampling for Low-Cost and Accurate Ehrenfest Modeling of Cavity Quantum Electrodynamics
An economic modeling approach for cavity quantum electrodynamics is provided by mean-field dynamics, wherein the optical field is described classically while a self-consistent interaction with quantum emitters is incorporated through the Ehrenfest theorem. However, conventional implementations of mean-field dynamics are known to suffer from a catastrophic leakage of zero-point energy, to lose accuracy in the short-cavity limit, and to require large numbers of trajectories to be sampled. Here, we address these three shortcomings within a single integrated approach. This approach builds on our recently proposed modification of the Ehrenfest theorem, referred to as decoupled mean-field (DC-MF) dynamics, in combination with a focused sampling scheme that enforces zero-point energy at the single-trajectory level. The approach is shown to yield high accuracy in both short and long-cavity limits while reaching convergence within a minimal amount of trajectories.
pubs.acs.org
December 1, 2025 at 4:59 AM
Our paper has been selected as the cover of Journal of Chemical Physics!🎉

We showed that self-consistent mixed quantum-classical (MQC) dynamics can reproduce persistent yet anharmonic Rabi oscillations, providing a new perspective for MQC approach for quantum systems.

doi.org/10.1063/5.02...
June 23, 2025 at 4:10 PM
Reposted by Ming-Hsiu Hsieh
Team member Ming-Hsiu Hsieh shows anharmonicities arising when coupling harmonic classical and quantum systems.

This work just appeared in the Journal of Chemical Physics @aip.bsky.social, as part of the Emerging Investigators Special Collection.

pubs.aip.org/aip/jcp/arti...
Mixed quantum–classical dynamics yields anharmonic Rabi oscillations
We apply a mixed quantum–classical (MQC) approach to the quantum Rabi model, involving a classical optical field coupled self-consistently to a quantum two-leve
pubs.aip.org
June 11, 2025 at 5:47 PM
My first bluesky post here to memorize my talk in our theory seminar!
May 14, 2025 at 1:48 AM