@gen-chem.bsky.social and @peremiro.bsky.social verified ligand oxidation observed in Pr/Tb(III) EChem with DFT - showing the formation of a ligand centred radical upon oxidation!

Using a bidentate di(silylamido)silane ligand to isolate trivalent Ce/Pr/Tb complexes and tetravalent Ce/U. One of my first times with EChem - a skill I have really enjoyed developing! Gorgeous Ce(IV/III) redox couple and EChem of U(IV) we found couples from U(III) to U(VI)