Delius Lab
@mvdelius.bsky.social
1.6K followers
660 following
38 posts
Supramolecular chemistry, dynamic covalent networks and functional materials
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Delius Lab
@mvdelius.bsky.social
· Sep 16
Solution-phase stabilization of a cyclocarbon by catenane formation
Cyclo[N]carbons, molecular rings consisting solely of N carbon atoms, have previously been studied in the gas phase and on surfaces at cryogenic temperatures, but they are generally considered too rea...
doi.org
Reposted by Delius Lab
Reposted by Delius Lab
ChemComm
@chemcomm.rsc.org
· Jun 11
Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photoluminescence
Organic radicals and diradicaloids that are both stable and luminescent are promising candidates for molecular qubits in quantum technologies. Here we report two new carbazole-functionalized…
buff.ly
Delius Lab
@mvdelius.bsky.social
· Jun 10
Solvent‐Induced Chirality Inversion in Propeller‐Shaped PDI Oligomers with Bright Circularly Polarized Luminescence
A highly luminescent propeller-shaped PDI hexamer exhibiting solvent-responsive circularly polarized luminescence (CPL) was synthesized via a one-pot reaction. The propeller chirality undergoes rever...
onlinelibrary.wiley.com
Reposted by Delius Lab
ChemComm
@chemcomm.rsc.org
· Jun 3
Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photoluminescence
Organic radicals and diradicaloids that are both stable and luminescent are promising candidates for molecular qubits in quantum technologies. Here we report two new carbazole-functionalized…
pubs.rsc.org
Delius Lab
@mvdelius.bsky.social
· May 7
Synergistic Co‐Recycling: Selective Oxidation of Polyethylene to Dicarboxylic Acids over Spent LiCoO2 Cathodes
This work introduces a co-upcycling strategy to simultaneously valorize waste polyethylene and spent lithium-ion batteries. By repurposing retired LiCoO2 cathode materials as catalysts, we demonstrat...
doi.org
Reposted by Delius Lab
Delius Lab
@mvdelius.bsky.social
· Apr 14
Decimeter-length elastic organic crystals capable of mechanical post-processing and optical waveguide modulation at 77 K
The development of decimeter-length organic crystals that remain elastic, functional, and machinable at extremely low temperatures, such as in liquid nitrogen (LN) environments, is a great challenge. ...
pubs.rsc.org
Delius Lab
@mvdelius.bsky.social
· Mar 20
Delius Lab
@mvdelius.bsky.social
· Mar 20
Delius Lab
@mvdelius.bsky.social
· Feb 26
Reposted by Delius Lab
Reposted by Delius Lab
Ivan Aprahamian
@aprahamian.bsky.social
· Jan 16
Delius Lab
@mvdelius.bsky.social
· Feb 7
Molecular Design for Dual Circularity: Polyester with Complementary Mechanical and Chemical Recyclability under Mild Conditions
A dual circularity concept was demonstrated to prevent plastic waste accumulation, where rational design paved the way. Apart from fully recovery of mechanical and thermal properties after as many as...
doi.org
Delius Lab
@mvdelius.bsky.social
· Jan 28
Ring‐in‐Ring Assembly Facilitates the Synthesis of a [12]Cycloparaphenylene ABC‐Type [3]Catenane
By threading a secondary ammonium salt through the crown ether and closing the third ring via CuAAC click reaction, we obtained a rare ABC-type hetero-[3]catenane comprising [12]CPP, 24-crown-8 and a...
onlinelibrary.wiley.com
Reposted by Delius Lab
Gav Armstrong
@nchemgav.bsky.social
· Jan 28
Delius Lab
@mvdelius.bsky.social
· Jan 20
Selective Synthesis of Z-Michael Acceptors via Hydroalkylation of Conjugated Alkynes
Hydroalkylation of terminal alkynes is a powerful approach to the synthesis of disubstituted alkenes. However, its application is largely unexplored in the synthesis of α,β-unsaturated carbonyls, whic...
pubs.acs.org
Reposted by Delius Lab
Delius Lab
@mvdelius.bsky.social
· Dec 9
A Helical Tubular Dyad of [9]Cycloparaphenylene: Synthesis, Chiroptical Properties and Post‐Functionalization
Employing the site-specific functionalization strategy, a radially conjugated, helical tubular molecule has been constructed by covalently connecting [9]cycloparaphenylenes with three sp-hybridized a....
onlinelibrary.wiley.com
Reposted by Delius Lab
